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Long-range excitations in time-dependent density functional theory

14th Nov 2006, 01:25 GMT

Neepa T. Maitra and David G. Tempel Adiabatic time-dependent density functional theory fails for excitations of a heteroatomic molecule composed of two open-shell fragments at large separation. Strong frequency dependence of the exchange-correlation kernel is necessary for both local and charge-transfer excitations. The root of this i ... [J. Chem. Phys. 125, 184111 (2006)] published Mon Nov 13, 2006.

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